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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2023 Volume 33, Issue 3, Pages 390–392 (Mi mendc406)

This article is cited in 3 papers

Communications

Radiolytic redistribution of H and O atoms in acetylacetone

D. A. Uchkina, A. V. Ponomarev

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Compared to ambient conditions, radiolysis of boiling acetylacetone almost halved the yield of C–OH bond cleavage and doubled the redistribution of H atoms

Keywords: acetylacetone, 4-hydroxypent-3-en-2-one, pentane-2,4-dione, radiolysis, boiling, radical cation, proton transfer, isomers.

Language: English

DOI: 10.1016/j.mencom.2023.04.029



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