Mendeleev Commun., 2023 Volume 33, Issue 3, Pages 390–392
(Mi mendc406)
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3 papers
Communications
Radiolytic redistribution of H and O atoms in acetylacetone
D. A. Uchkina ,
A. V. Ponomarev A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Compared to ambient conditions, radiolysis of boiling acetylacetone almost halved the yield of C–OH bond cleavage and doubled the redistribution of H atoms
Keywords:
acetylacetone, 4-hydroxypent-3-en-2-one, pentane-2,4-dione, radiolysis, boiling, radical cation, proton transfer, isomers.
Language: English
DOI:
10.1016/j.mencom.2023.04.029
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