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Relationship between the cycloaddition activation energy and thermal effect in solutions

V. G. Uryadov, E. N. Ofitserov

Kazan National Research Technological University, Kazan, Russian Federation

Abstract: Based on the concept of the transition state of the reactions in a liquid phase as a Prigogine dissipative structure, the following equation has been derived establishing the relationship between the cycloaddition activation energy and thermal effect in a solution: (E_aL₂L₃)/Q = Kx².

Language: English

DOI: 10.1070/MC2003v013n06ABEH001729

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