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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2003 Volume 13, Issue 2, Pages 46–48 (Mi mendc3949)

This article is cited in 3 papers

1H NMR characterization of intermediates formed by the activation of zirconocenes with methylaluminoxane at high Al/Zr ratios

E. P. Talsia, K. P. Bryliakova, N. V. Semikolenovaa, V. A. Zakharova, M. Ystenesb, E. Rytterc

a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b Department of Chemical Engineering, Norwegian Univeristy of Science and Technology, Trondheim, Norway
c Statoil Research Centre, Trondheim, Norway

Abstract: Cation-like intermediates formed by the activation of zirconocenes L2ZrCl2 [L2 are cyclopentadienyl (Cp), indenyl (Ind) and fluorenyl (Flu) ligands] with methylaluminoxane (MAO) at high Al/Zr ratios were characterised by 1H NMR spectroscopy

Language: English

DOI: 10.1070/MC2003v013n02ABEH001689



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