This article is cited in 6 papers

Unusual catalytic effect of halide anions in the protolytic dissociation of indium(III) octaphenyltetraazaporphyrins

S. S. Ivanova, P. A. Stuzhin

Department of Organic Chemistry, Ivanovo State University of Chemical Technology, Ivanovo, Russian Federation

Abstract: Chloro(octaphenyltetraazaporphyrinato)indium(III) [(Cl)InOPTAP] dissociates easily in slightly acidified dichloromethane solutions (0.001–0.01 M CF₃COOH) after addition of tetraethylammonium chloride; the observed catalytic effect of chloride anions is due to their additional cis-coordination to the In atom with formation of the dianionic complex [(Cl)₃InOPTAP]^2–.

Language: English

DOI: 10.1070/MC2003v013n01ABEH001704

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