This article is cited in 1 paper

Resolution and racemization of nonbenzenoid atropenantiomers

P. V. Novikov^a, O. R. Malyshev^b, K. A. Lyssenko^c, R. G. Kostyanovsky<sup>a

a</sup> N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The three-step synthesis of adduct 3 has been reinvestigated; enantiomers 3a and 3b have been separated by enantioselective chromatography and the racemization barrier of 3a was determined as ΔG^≠ = 24.4 kcal mol⁻¹ (16 °C).

Language: English

DOI: 10.1070/MC2004v014n06ABEH002049

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