This article is cited in 11 papers

Regioselectivity of 1,1-dimethylallene allylboration: synthesis of isomeric 6- and 7-methylene-3-borabicyclo[3.3.1]nonanes

S. Yu. Erdyakov^a, M. E. Gurskii^a, A. V. Ignatenko^a, Yu. N. Bubnov<sup>b

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A dramatical difference in the stereoselectivity of 1,1-dimethylallene allylboration with allyl(chloro)- and triallylboranes has been revealed and applied to the synthesis of isomeric 7-methylene-6,6-dimethyl- and 6-(1-methylethylidene)-3-borabicyclo[3.3.1]-nonanes.

Language: English

DOI: 10.1070/MC2004v014n06ABEH002053

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