This article is cited in 12 papers

Reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with butane-2,3-diol

N. G. Khusainova^a, O. A. Mostovaya^a, N. M. Azancheev^b, I. A. Litvinov^b, D. B. Krivolapov^b, R. A. Cherkasov<sup>a

a</sup> Department of Chemistry, V.I. Ul'yanov-Lenin Kazan State University, Kazan, Russian Federation
^b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with (rac)-butane-2,3-diol at temperatures below 0 °C leads to the formation of a hydrospirophosphorane containing both a diazaphospholene and a dioxaphospholane ring system and a β-hydroxyalkoxy-1,2,3-diazaphospholene. On heating, these products form a hydrospirotetraoxaphosphorane, its tautomeric monocyclic β-hydroxyalkylphosphite and N-acetyl-N’-isopropylidene-hydrazine.

Language: English

DOI: 10.1070/MC2004v014n05ABEH001926

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