L. M. Abdrakhmanova, V. F. Mironov, T. A. Baronova, M. N. Dimukhametov, D. B. Krivolapov, I. A. Litvinov, A. A. Balandina, Sh. K. Latypov, A. I. Konovalov, “A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone”, Mendeleev Commun., 2006, Volume 16, Issue 6,Pages <nobr>320

This article is cited in 19 papers

A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone

L. M. Abdrakhmanova, V. F. Mironov, T. A. Baronova, M. N. Dimukhametov, D. B. Krivolapov, I. A. Litvinov, A. A. Balandina, Sh. K. Latypov, A. I. Konovalov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The reaction of 2-(2-oxo-1,2-diphenylethoxy)- and 2-(1-methyl-3-oxobut-2-en-1-yloxy)benzo[d]-1,3,2-dioxaphospholes with hexafluoroacetone is a versatile approach to the synthesis of 6,6-bis(trifluoromethyl)-3,4-diphenyl-1,1-phenylenedioxy- 1-phospha-2,5,7-trioxabicyclo[2.2.1]heptane and 3,5-dimethyl-7,7-bis(trifluoromethyl)-1,1-phenylenedioxy-1-phospha-2,6,8-trioxabicyclo[2.2.1]oct-3-ene, respectively, in high yields

Language: English

DOI: 10.1070/MC2006v016n06ABEH002414