This article is cited in 12 papers

Unusual binuclear alkoxomolybdenum(V) complex free of oxo groups: synthesis, structure and IR spectra

N. V. Bardina^a, T. A. Bazhenova^a, K. A. Lyssenko^b, M. Yu. Antipin^b, Yu. M. Shulga^a, T. A. Savinykh^a, A. F. Shestakov<sup>a

a</sup> Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The interaction of MoCl₅ with NaOMe in methanol led to the formation of a new neutral binuclear molybdenum(V) alkoxo complex with Cl ligands, trans-[Cl(OMe)₃Mo(μ-OMe)₂Mo(OMe)₃Cl]; the complex was characterised by X-ray analysis, IR spectroscopy and DFT quantum-chemical calculations.

Language: English

DOI: 10.1070/MC2006v016n06ABEH002426