This article is cited in 4 papers

Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode

V. A. Kurmaz^a, A. B. Ershler<sup>b

a</sup> Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The acid-catalysed protolysis of intermediates, formed either during one-electron reduction of substituted arylmercury salt (C₆F₅HgBr) or by the adsorption of bis(arylalkynyl)mercury compound [(PhC≡C)₂Hg] on a Hg electrode has been found in lowacidic media (3 < pH < 6), whereas it was not observed in alkylmercury salt (PrⁿHgOAc).

Language: English

DOI: 10.1070/MC2006v016n04ABEH002259

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