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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2006 Volume 16, Issue 4, Pages 218–220 (Mi mendc3594)

This article is cited in 12 papers

Synthesis of 4-benzoyl-1,2,6-trialkyl-1,2,4,6-tetrazepane-5-thiones by the interaction of 1,2-dialkyldiaziridines with benzoyl isothiocyanate in ionic liquids

A. V. Shevtsova, V. V. Kuznetsova, K. A. Lyssenkob, P. A. Belyakova, N. N. Makhovaa

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: An interaction of 1,2-dialkyldiaziridines with benzoyl isothiocyanate in the room temperature ionic liquids [emim] [BF4] and [emim] [PF6] unexpectedly resulted in previously unknown 4-benzoyl-1,2,6-trialkyl-1,2,4,6-tetrazepane-5-thiones; the reaction was carried out by the cleavage of the C–N and of the N–N bonds of the diaziridine ring.

Language: English

DOI: 10.1070/MC2006v016n04ABEH002380



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