This article is cited in 5 papers

Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation

N. V. Volchkov, M. B. Lipkind, A. V. Zabolotskikh, A. V. Ignatenko, O. M. Nefedov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The gas-phase pyrolysis of 1-chloro-1-fluoro-2-vinylcyclopropane and 1-chloro-1-fluoro-2-methyl-2-vinylcyclopropane at 305–360 °C afforded 4-chloro-4-fluorocyclopentenes and chlorofluorobutadienes as a result of competitive vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl isomerisation.

Language: English

DOI: 10.1070/MC2006v016n03ABEH002324

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