A. V. Eremkin, S. N. Molkov, O. V. Ershov, Ya. S. Kayukov, O. E. Nasakin, V. A. Tafeenko, E. V. Nurieva, “Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1<i>H</i>-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes”, Mendeleev Commun., 2006, Volume 16, Issue 2,Pages <nobr>115

This article is cited in 14 papers

Synthesis of 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-1H-pyridine-3,4,4-tricarbonitriles by the reaction of tetracyanoethylene with aldehydes

A. V. Eremkin^a, S. N. Molkov^a, O. V. Ershov^a, Ya. S. Kayukov^a, O. E. Nasakin^a, V. A. Tafeenko^b, E. V. Nurieva^b

^a Department of Chemistry, I.N. Ulyanov Chuvash State University, Cheboksary, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The reaction of tetracyanoethylene and isobutyraldehyde or 2-ethylbutanal in an excess of a hydrohalogen acid yields 2-halo-6-hydroxy-5,5-dimethyl(ethyl)-5,6-dihydro-3,4,4(1H)-pyridinetricarbonitriles, the crystal and molecular structures of which were characterised by IR, NMR, MS and X-ray analysis.

Language: English

DOI: 10.1070/MC2006v016n02ABEH002206