L. M. Abdrakhmanova, V. F. Mironov, T. A. Baronova, M. N. Dimukhametov, D. B. Krivolapov, I. A. Litvinov, R. Z. Musin, A. I. Konovalov, “Synthesis of spirophosphoranes containing a phosphorus–carbon bond using the reactions of substituted benzo[<i>d</i>]-1,3,2-dioxaphospholes with diethyl acetylenedicarboxylate”, Mendeleev Commun., 2007, Volume 17, Issue 5,Pages <nobr>284

This article is cited in 13 papers

Synthesis of spirophosphoranes containing a phosphorus–carbon bond using the reactions of substituted benzo[d]-1,3,2-dioxaphospholes with diethyl acetylenedicarboxylate

L. M. Abdrakhmanova, V. F. Mironov, T. A. Baronova, M. N. Dimukhametov, D. B. Krivolapov, I. A. Litvinov, R. Z. Musin, A. I. Konovalov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The reaction of 2-(2-oxo-1,2-diphenyl)ethoxy- and 2-(2-methylcarbonyl)phenyloxybenzo[d]-1,3,2-dioxaphospholes with diethyl acetylenedicarboxylate was used to synthesise 5,6-bis(ethoxycarbonyl)-3,4-diphenyl-1,1-phenylenedioxy-1-phospha-2,7-dioxabicyclo[2.2.1^1,4]hept-5-ene and 5-methyl-6,7-bis(ethoxycarbonyl)-1,1-phenylenedioxy-3,4-benzo-1-phospha-2,8-dioxabicyclo-[3.2.1^1,5]oct-6-ene in high yields.

Language: English

DOI: 10.1016/j.mencom.2007.09.012