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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2007 Volume 17, Issue 5, Pages 274–276 (Mi mendc3455)

This article is cited in 5 papers

High selectivity of fluorine atom addition to the asymmetric chemical bonds of C70 fullerene

E. Ya. Misochkoa, A. V. Akimova, V. A. Belova, D. A. Tyurinb, D. N. Laikovc

a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c Department of Chemistry, Temple University, Philadelphia, Pennsylvania, USA

Abstract: New assignment of EPR spectra of low-temperature F + C70 reaction products shows an unexpectedly high selectivity of the addition of the F atom to the asymmetric C=C bonds of C70 to form three C70F regioisomers only among the five possible ones.

Language: English

DOI: 10.1016/j.mencom.2007.09.008



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