This article is cited in 4 papers

The first example of a carbon label for interpreting the ¹³C NMR spectra of phthalocyanine metal complexes

V. E. Pushkarev^a, E. V. Shulishov^b, Yu. V. Tomilov^b, L. G. Tomilova<sup>a

a</sup> Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A carbon label has been introduced into phthalocyanine molecules in order to perform a correct assignment of signals in the ¹³C NMR spectra of planar and sandwich-type metal complexes. With europium and lutetium as examples, the introduction of the label and the use of DEPT-135, GATED and ¹H–¹³C COSY procedures enabled the recording and total assignment of signals in the ¹³C NMR spectra of homo- and heteronuclear three-decked phthalocyanines of rare-earth elements.

Language: English

DOI: 10.1016/j.mencom.2007.06.011

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