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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2007 Volume 17, Issue 3, Pages 183–185 (Mi mendc3420)

This article is cited in 7 papers

Formation of (1,2-dihydroxynaphth-4-yl)[tris(diethylamino)]-phosphonium bromides in the reaction of 1,2-naphthoquinones with tris(diethylamino)phosphine

A. V. Bogdanov, V. F. Mironov, N. R. Khasiyatullina, D. B. Krivolapov, I. A. Litvinov, A. I. Konovalov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The title reaction leads to the formation of betaines containing a phosphorus–carbon bond, 2-hydroxy-4-[tris(diethylamino)-phosphonium]naphthyl-1-ates, which react with bromine and moist acetone (or hydrogen bromide), as well as diethylammonium chloride, to give (1,2-dihydroxynaphth-4-yl)[tris(diethylamino)]phosphonium bromide derivatives.

Language: English

DOI: 10.1016/j.mencom.2007.05.018



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