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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2007 Volume 17, Issue 3, Pages 172–174 (Mi mendc3416)

This article is cited in 19 papers

Synthesis and molecular structure of seven isomers of C70(C2F5)10

N. B. Tamm, S. I. Troyanov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: A mixture of C70(C2F5)n (n = 8, 10, 12) compounds was synthesised by a reaction of C70 with C2F5I at 350 °C followed by HPLC separation; crystal structure determination for seven isomers of C70(C2F5)10 revealed a large variety of addition patterns most of which are unprecedented in the regiochemistry of [70]fullerene.

Language: English

DOI: 10.1016/j.mencom.2007.05.014



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