This article is cited in 4 papers

Communications

Crystal structure of tetrakis(triphenylphosphine)palladium(0)

T. S. Sukhikh, M. P. Davydova, A. V. Artem’ev

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Crystal structure of widely employed precatalyst [Pd(Ph₃P)₄] is reported. It crystallizes in P-3 space group [a = 19.0828(8) and c = 26.4423(18) Å] with six molecules per unit cell. It is demonstrated that the phase purity of this important compound can now be routinely controlled via powder X-ray diffraction analysis.

Keywords: tetrakis(triphenylphosphine)palladium(0), crystal structure, crystal packing, phase purity control, IR spectra, powder X-ray diffraction analysis.

Language: English

DOI: 10.1016/j.mencom.2023.02.007

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