This article is cited in 6 papers

Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte

E. V. Starodubtseva, O. V. Turova, M. G. Vinogradov, V. A. Ferapontov, I. V. Razmanov, S. G. Zlotin, A. S. Kucherenko

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The asymmetric hydrogenation of methyl levulinate to chiral γ-valerolactone has been performed with the recycling of a Ru^II–BINAP catalyst deposited on a solid organic polyelectrolyte; enantioselectivity up to 99% ee has been achieved at high conversion of substrate after three recycles of the catalyst.

Language: English

DOI: 10.1016/j.mencom.2007.01.008

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