This article is cited in 17 papers

Unexpected formation of an oxetane cycle by oxidation of diacetonide of 20-hydroxyecdysone with oxygen in an alkaline medium

V. N. Odinokov^a, I. V. Galyautdinov^a, A. Sh. Ibragimova^a, N. A. Veskina^a, L. M. Khalilov^a, F. M. Dolgushin^b, Z. A. Starikova<sup>b

a</sup> Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The diacetonides of 9α,14α-epoxy-14-deoxy-20-hydroxyecdysone and 14α-hydroperoxy-14-deoxy-20-hydroxyecdysone have been obtained by the interaction of diacetonide of 20-hydroxyecdysone with a solution of lithium in liquid ammonia and following treatment with ammonia chloride and atmospheric oxygen.

Language: English

DOI: 10.1016/j.mencom.2008.09.023

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