This article is cited in 25 papers

Highly regioselective nickel-catalyzed hydrodefluorination of pentafluoroacetanilide

S. A. Prikhod'ko, N. Yu. Adonin, D. E. Babushkin, V. N. Parmon

G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: A highly regioselective reaction of pentafluoroacetanilide hydrodefluorination, which proceeds under the action of zinc in the presence of nickel complexes, leading to the formation of 2,3,4,5-tetra- and 3,4,5-trifluoroacetanilide was observed.

Keywords: Nickel, C-F bond activation, catalysis, fluoroanilines.

Language: English

DOI: 10.1016/j.mencom.2008.07.015

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