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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2008 Volume 18, Issue 2, Pages 67–68 (Mi mendc3248)

This article is cited in 1 paper

Photochemical reactions of trimethylene sulfide radical cations in Freon matrices at 77K

M. Ya. Melnikov, V. N. Belevskii, A. D. Kalugina, V. I. Pergushov, D. A. Tyurin

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Photobleaching (λ=436nm) of trimethylene sulfide radical cations (λmax≈460nm, ϵmax≈345dm3mol–1cm–1) stabilised in different Freon matrices at 77K results in the formation of distonic radical cations CH2CHSHCH2·+.

Language: English

DOI: 10.1016/j.mencom.2008.03.002



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