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JOURNALS
// Mendeleev Communications
// Archive
Mendeleev Commun.,
2008
Volume 18,
Issue 2,
Pages
67–68
(Mi mendc3248)
This article is cited in
1
paper
Photochemical reactions of trimethylene sulfide radical cations in Freon matrices at 77K
M. Ya. Melnikov
,
V. N. Belevskii
,
A. D. Kalugina
,
V. I. Pergushov
,
D. A. Tyurin
Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract:
Photobleaching (
λ
=436nm) of trimethylene sulfide radical cations (
λ
max
≈460nm, ϵ
max
≈345dm
3
mol
–1
cm
–1
) stabilised in different Freon matrices at 77K results in the formation of distonic radical cations CH
2
CHSHCH
2
·+
.
Language:
English
DOI:
10.1016/j.mencom.2008.03.002
Fulltext:
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