This article is cited in 9 papers

Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion

V. D. Kiselev

Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: The volumes of electrostriction of the ions of lithium perchlorate are in a linear relation with the solvent electrostriction parameter ∂(1/ϵ)/∂p but the volume changes of ion pair transition state of electrophilic addition of aryl sulfenyl chloride to styrene and cyclohexene have the slope about 20 times less.

Keywords: sulfenyl chloride; volume of activation; solvent effect; electrostriction; mechanism.

Language: English

DOI: 10.1016/j.mencom.2008.01.022

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