This article is cited in 5 papers

A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH₂)_n–Y molecules

K. B. Nuzhdin^a, A. V. Kobzarenko^a, I. I. Barabanov^b, V. I. Feldman<sup>ac

a</sup> Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^c N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The radical cations of aminoamides Me₂N(CH₂)_nC(O)NMe₂ and aminoethers Me₂N(CH₂)_nOMe reveal selective photoinduced intramolecular H transfer from methylene bridge at a specific chain length (n = 3).

Keywords: radical cations, EPR, bifunctional compounds.

Language: English

DOI: 10.1016/j.mencom.2009.09.012

Bibliographic databases:

•