N. Yu. Adonin, S. A. Prikhod'ko, V. V. Bardin, V. N. Parmon, “The first example of the ortho-directing effect of the weakly coordinating substituent [–BF3]– in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion”, Mendeleev Commun., 2009, Volume 19, Issue 5,Pages 260

This article is cited in 15 papers

The first example of the ortho-directing effect of the weakly coordinating substituent [–BF₃]^– in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion

N. Yu. Adonin^a, S. A. Prikhod'ko^a, V. V. Bardin^b, V. N. Parmon^a

^a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The pentafluorophenyltrifluoroborate anion undergoes hydrodefluorination under the action of zinc in the presence of nickel complexes turning into the 2,3,4,5-tetrafluoroborate anion.

Keywords: hydrodeboration, nickel complexes, fluorinated organoboron compounds.

Language: English

DOI: 10.1016/j.mencom.2009.09.009