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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2023 Volume 33, Issue 1, Pages 93–94 (Mi mendc318)

This article is cited in 1 paper

Communications

Selective synthesis of clamshell-type bis-phthalocyanine bearing tetrachlorocyclotriphosphazene intramolecular bridge

A. Yu. Tolbina, V. K. Brelb, V. E. Pushkareva

a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The selective synthesis of clamshell-type bis-phthalocyanine was performed using cyclotriphosphazene as a peripheral spacer. The spectral characteristics of the target dye are similar to those of most H-dimers, and the reaction can be considered conditionally selective with respect to the cis-isomer

Keywords: phthalocyanines, phosphazenes, H-dimers, clamshell dimers, dyes, UV-VIS, NMR.

Language: English

DOI: 10.1016/j.mencom.2023.01.029



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