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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 4, Pages 217–219 (Mi mendc3175)

This article is cited in 13 papers

Synthesis of 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes and isomeric 1,3- and 1,4-bis[3(4)-nitrofuroxan-4(3)-yl]benzenes

I. V. Ovchinnikov, A. O. Finogenov, M. A. Epishina, Yu. A. Strelenko, N. N. Makhova

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The 1,3- and 1,4-bis(3-nitrofurazan-4-yl)benzenes have been synthesized by dehydration of 1,3- and 1,4-bis(2-aminoglyoximo- 1-yl)benzenes followed by oxidation of amino groups. The 1,3- and 1,4-bis(3-nitrofuroxan-4-yl)benzenes have been prepared by nitrozylation of tetrapotassium salts of 1,3- and 1,4-bis(2,2-dinitro-1-oximinoethyl)benzenes and thermally isomerized to 1,3- and 1,4-bis(4-nitrofuroxan-3-yl)benzenes.

Language: English

DOI: 10.1016/j.mencom.2009.07.015



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