This article is cited in 6 papers

Reduction fragmentation of the [Mn₁₂O₁₂(O₂CCHCl₂)₁₆(H₂O)₄] oxocarboxylate cluster to [Mn₆O₂(O₂CCHCl₂)₁₀(MeCN)₄]

L. A. Kushch, G. V. Shilov, R. B. Morgunov, E. B. Yagubskii

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: The reaction of the [Mn₁₂O₁₂(O₂CCHCl₂)₁₆(H₂O)₄] cluster with tetrathiotetracene triiodide has been studied and, for the first time, reduction fragmentation of Mn₁₂ cluster to Mn₆ cluster has been found.

Keywords: oxocarboxylate Mn12 cluster, tetrathiotetracene, single molecule magnets, hexanuclear cluster.

Language: English

DOI: 10.1016/j.mencom.2009.05.021

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