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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 3, Pages 144–146 (Mi mendc3148)

This article is cited in 18 papers

An unexpected transformation of 3,4-bis(isocyanato)furoxan into 3,3’-bi(1,2,4-oxadiazol-5-one)

I. V. Ovchinnikova, K. A. Lyssenkob, N. N. Makhovaa

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A transformation of 3,4-bis(isocyanato)furoxan into 3,3’-bi(1,2,4-oxadiazol-5-one) by the action of water was unexpectedly found. The structure of the product was established by spectroscopic and X-ray methods; a mechanism of the transformation is suggested.

Language: English

DOI: 10.1016/j.mencom.2009.05.010



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