This article is cited in 8 papers

Synthesis and crystal structure of 5-carbaphosphatranes containing a four-membered cycle

V. F. Mironov^ab, Yu. Yu. Kotorova^a, L. M. Burnaeva^a, A. A. Balandina^b, Sh. K. Latypov^b, A. B. Dobrynin^b, A. T. Gubaidullin^b, I. A. Litvinov^b, R. Z. Musin^b, I. V. Konovalova<sup>a

a</sup> Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
^b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: 4,4-Bis(trifluoromethyl)-4,5-dihydro-2-phenylbenzo[e]- and 4,4-bis(trifluoromethyl)-4,5-dihydro-2-phenyl-(4’-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-ones react with hexafluoroacetone to form unusual propeller type structures – 3,3,10,10-tetrakis-(trifluoromethyl)-1-phenyl-6,7-benzo- and 3,3,10,10-tetrakis(trifluoromethyl)-1-phenyl-6,7-(4’-chlorobenzo)-2,4,8,9-tetraoxa-1-phosphatricyclo[3.3.2.01,5]decenes (5-carbaphosphatrane derivatives), the structure of which has been determined by NMR spectroscopy and single crystal X-ray diffraction analysis.

Language: English

DOI: 10.1016/j.mencom.2009.01.014

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