This article is cited in 6 papers

Unexpected mode of reactivity in nitrosation of cis-1,1-dichloro-2,3-diphenylcyclopropane with NOCl·2SO₃

O. B. Bondarenko^a, A. Yu. Gavrilova^a, V. V. Polunina^a, Z. A. Starikova^b, N. V. Zyk^a, N. S. Zefirov<sup>a

a</sup> Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: cis-1,1-Dichloro-2,3-diphenylcyclopropane reacts with NOCl·2SO₃ to provide new heterocyclic compounds, N-oxide of 3,3-dichloro-2,4-diphenylazetine and 4,4-dichloro-3,5-diphenylisoxazoline, with 45 and 30% yields, respectively. The structure of the products was unambiguously stated by X-ray crystallography.

Keywords: cyclopropane, nitrosation, azetine N-oxide, isoxazoline, X-ray crystallography.

Language: English

DOI: 10.1016/j.mencom.2009.01.005

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