This article is cited in 12 papers

The first example of the Schmidt reaction in ionic liquids

M. A. Epishina^a, A. S. Kulikov^a, N. V. Ignat'ev^b, M. Schulte^b, N. N. Makhova<sup>a

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Ionic Liquid Research Laboratory, Merck KGaA, Darmstadt, Germany

Abstract: The Schmidt reaction of aryl methyl ketones in ionic liquids (optimally in 1-ethyl-3-methylimidazolium triflate with CF₃SO₃H additive) proceeds at 40°C within 10–30 h to give the corresponding acetanilides in good yields.

Language: English

DOI: 10.1016/j.mencom.2010.11.011

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