This article is cited in 22 papers

The Suzuki–Miyaura cross-coupling of bromo- and chloroarenes with arylboronic acids in supercritical carbon dioxide

I. V. Kuchurov, A. A. Vasil'ev, S. G. Zlotin

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Haloarenes ArHal (Hal=Br, Cl) react with arylboronic acids in supercritical carbon dioxide in the presence of a system comprising Pd(OCOCF₃)₂/Buchwald phosphine ligand/potassium carbonate (phosphate)/18-crown-6 to yield the corresponding cross-coupling products in high yields; all chlorine atoms in di- and tetrachloroarenes are replaced by aryl groups under the proposed conditions.

Language: English

DOI: 10.1016/j.mencom.2010.05.005

Bibliographic databases:

•