This article is cited in 12 papers

Thermodynamics of atomic ordering in nonstoichiometric transition metal monoxides

A. A. Rempel, A. A. Valeeva

Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

Abstract: The XRD studies of structural vacancy redistribution in titanium, vanadium and niobium monoxides undergoing atomic-vacancy ordering or structural vacancy clusterization have shown the necessity of a many-cluster approach to model the free energy function of nonstoichiometric monoxides.

Keywords: thermodynamics, phase diagram, entropy, structural vacancies, atomic defects, cluster defects, cluster variation method, titanium.

Language: English

DOI: 10.1016/j.mencom.2010.03.012

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