L. M. Abdrakhmanova, V. F. Mironov, M. N. Dimukhametov, D. B. Krivolapov, I. A. Litvinov, “Synthesis of new spirophosphoranes bearing the phosphorus–carbon bond by cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo- 1,3,2-dioxaphosphole with activated carbonyl compounds”, Mendeleev Commun., 2010, Volume 20, Issue 1,Pages <nobr>41

This article is cited in 12 papers

Synthesis of new spirophosphoranes bearing the phosphorus–carbon bond by cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo- 1,3,2-dioxaphosphole with activated carbonyl compounds

L. M. Abdrakhmanova, V. F. Mironov, M. N. Dimukhametov, D. B. Krivolapov, I. A. Litvinov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: Cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo-σ³λ³-1,3,2-dioxaphosphole with chloral, hexafluoroacetone, mezoxalic acid diethyl ester and trifluoropyruvic acid ethyl ester are a versatile approach to the synthesis of spirophosphoranes bearing a phosphorus–carbon bond with a high yield and stereoselectivity.

Language: English

DOI: 10.1016/j.mencom.2010.01.016