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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 1, Pages 39–40 (Mi mendc2984)

This article is cited in 4 papers

Unusual synthesis of phosphorus-containing 1,3-oxazine- 2,4-dione of zwitter-ionic structure by the N-reaction of cyano-carbanion with 2,4,6-trinitrofluorobenzene

Yu. G. Gololobov, V. N. Khrustalev, N. V. Slepchenkov, A. S. Peregudov, M. Yu. Antipin

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A phosphonium zwitterion containing a carbamate moiety is a cyano-carbanion, and it reacts with 2,4,6-trinitrofluorobenzene as an N-nucleophile to form substituted oxazine-2,4-dione and ethyl fluoride.

Language: English

DOI: 10.1016/j.mencom.2010.01.015



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