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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2011 Volume 21, Issue 6, Pages 346–348 (Mi mendc2968)

This article is cited in 6 papers

Synthesis of bis-phosphonium salts from 6-bromo-1,2-naphthoquinone and α,ω-bis(diphenylphosphino)alkanes

N. R. Khasiyatullina, V. F. Mironov, A. V. Bogdanov, D. B. Krivolapov, I. A. Litvinov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: 1,4-Bis(diphenylphosphino)butane and 1,5-bis(diphenylphosphino)pentane add two molecules of 6-bromo-1,2-naphthoquinone to afford bis-ylides which on treatment with protic acids are converted into the corresponding P,P’-bis(7-bromo-3,4-dihydroxy-1-naphthyl)-substituted bis-phosphonium salts.

Language: English

DOI: 10.1016/j.mencom.2011.11.019



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