This article is cited in 1 paper

Sodium borohydride reduction of 4-aryl-N-trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline ozonide

A. G. Tolstikov, R. G. Savchenko, S. R. Afonkina, E. S. Lukina, D. V. Nedopekin, L. M. Khalilov, V. N. Odinokov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: Reduction of the title ozonide with 1 equiv. of sodium borohydride in ethanol leads to the transformation of the ozonide moiety into d-lactone one, whereas the use of 5 equiv. of the reductant affords the corresponding 1,5-diol, with N-deacylation occurring in all cases.

Keywords: δ-Lactones, ozonides, reduction.

Language: English

DOI: 10.1016/j.mencom.2011.09.019

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