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// Mendeleev Communications
// Archive
Mendeleev Commun.,
2011
Volume 21,
Issue 4,
Pages
192–193
(Mi mendc2912)
This article is cited in
4
papers
Efficient synthesis of β-hydroxy sulfides by microwave-promoted ring opening in (+)-3-carene
trans
-epoxide with sodium thiolates
A. M. Agafontsev
a
,
N. B. Gorshkov
a
,
A. V. Tkachev
ab
a
N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b
Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
Abstract:
Reaction of (+)-3-carene
trans
-epoxide with sodium thiolates in methanolic solution in a microwave oven at 140°C for 35–40min affords corresponding (1
S
,3
S
,4
S
,6
R
)-4-sulfanylcaran-3-ols in 75–95% yields.
Language:
English
DOI:
10.1016/j.mencom.2011.07.006
Fulltext:
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Supplementary materials:
Supplementary_data_1.pdf
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