This article is cited in 25 papers

A Mild and Efficient Synthesis of 3-Hetarylamino-s-Tetrazines

A. B. Sheremetev^a, N. V. Palysaeva^a, M. I. Struchkova^a, K. Yu. Suponitsky<sup>b

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: 3,6-Bis(3,5-dimethylpyrazol-1-yl)-s-tetrazine reacts with weakly based hetarylamines such as aminofurazans, aminoimidazoles, aminotriazoles, aminotetrazoles, or aminotetrazines on heating in MeCN in the presence of M₂CO₃ (M = K, Cs) to afford 3-hetaryl- amino-s-tetrazines, the products of 3,5-dimethylpyrazolyl group displacement.

Language: English

DOI: 10.1016/j.mencom.2012.11.007

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