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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2012 Volume 22, Issue 4, Pages 184–186 (Mi mendc2783)

This article is cited in 7 papers

Ru–BINAP-catalyzed asymmetric hydrogenation of keto esters in high pressure carbon dioxide

O. V. Turovaa, I. V. Kuchurova, E. V. Starodubtsevaa, V. A. Ferapontova, N. S. Ikonnikovb, S. G. Zlotina, M. G. Vinogradova

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Asymmetric hydrogenation of ethyl 4-chloro-3-oxobutyrate and dimethyl acetylsuccinate in high pressure CO2 using [RuCl2(C6H6)]2–(R)-BINAP as the catalyst provides high ee values for the products.

Language: English

DOI: 10.1016/j.mencom.2012.06.003



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