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JOURNALS
// Mendeleev Communications
// Archive
Mendeleev Commun.,
2012
Volume 22,
Issue 4,
Pages
184–186
(Mi mendc2783)
This article is cited in
7
papers
Ru–BINAP-catalyzed asymmetric hydrogenation of keto esters in high pressure carbon dioxide
O. V. Turova
a
,
I. V. Kuchurov
a
,
E. V. Starodubtseva
a
,
V. A. Ferapontov
a
,
N. S. Ikonnikov
b
,
S. G. Zlotin
a
,
M. G. Vinogradov
a
a
N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Asymmetric hydrogenation of ethyl 4-chloro-3-oxobutyrate and dimethyl acetylsuccinate in high pressure CO
2
using [RuCl
2
(C
6
H
6
)]
2
–(
R
)-BINAP as the catalyst provides high
ee
values for the products.
Language:
English
DOI:
10.1016/j.mencom.2012.06.003
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