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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2012 Volume 22, Issue 2, Pages 70–72 (Mi mendc2742)

This article is cited in 17 papers

CoII complex of N-[2-(phenylseleno)cyclohexyl]-N-(pyridin-2-ylmethylene) amine: Synthesis, electrochemistry and catalysis of triphenylphosphine and norbornene oxidation by nitrous oxide

A. N. Chernysheva, E. K. Beloglazkina, A. A. Moiseeva, R. L. Antipin, N. V. Zyk, N. S. Zefirov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The selenoorganic ligand N-[2-(phenylseleno)cyclohexyl]-N-(pyridin-2-ylmethylene)amine and its coordination compound with CoCl2 have been obtained and investigated by cyclic voltammetry. The oxidation reactions of triphenylphosphine and norbornene using N2O as the oxidant and the synthesized complex as a catalyst are described.

Keywords: complex, cobalt(II), elecrochemistry, oxidation, catalysis.

Language: English

DOI: 10.1016/j.mencom.2012.03.005



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