This article is cited in 1 paper

Communications

Retention of a Six-Membered Ring in the Reaction of 2-dialkylaminobenzo[e]-1,3,2-dioxaphosphinin-4-ones with Pentafluorobenzaldehyde: O,N-exchange at Phosphorus

V. F. Mironov^ab, L. M. Burnaeva^b, G. A. Ivkova^b, A. B. Dobrynin^a, E. V. Mironova^a, I. A. Litvinov<sup>a

a</sup> A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: The title reaction leads to the formation of diastereoisomeric 2-[(dialkylamino)(pentafluorophenyl)methyl]benzo[e]-1,3,2-dioxaphosphinine-2,4-diones in a ratio of 70 : 30. The configuration of chiral centres for the preferable diastereoisomer was determined by single crystal X-ray diffraction analysis.

Language: English

DOI: 10.1016/j.mencom.2013.05.018

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