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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2014 Volume 24, Issue 6, Pages 336–337 (Mi mendc2571)

This article is cited in 7 papers

Communications

Preparative synthesis of selectively substituted 1,6-anhydro-α-D-galactofuranose derivatives

V. B. Krylov, D. A. Argunov, N. E. Nifantiev

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Heating of trisodium salt of allyl 3-O-benzyl-2,5,6-tri-O-sulfonato-β-D-galactofuranoside with pyridinium chloride in dioxane affords 1,6-anhydro-3-O-benzyl-α-D-galactofuranose which was regioselectively acylated to give useful precursors for oligosaccharide synthesis.

Language: English

DOI: 10.1016/j.mencom.2014.11.006



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