This article is cited in 6 papers

Communications

Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids

A. A. Vasil'ev, S. G. Zlotin

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Palladium-catalyzed potassium carbonate-assisted reaction between diethyl malonate and allyl acetate in the presence of 1,3-dialkyl-imidazolium ionic liquids (ILs) as solvents or phase transfer catalysts affords major monoallylation product, whereas in the presence of 1,2,3-trialkylimidazolium or quaternary ammonium/phosphonium ILs diallylation product is preferably formed. These procedures are extended to some other CH-acids and allylic acetates.

Language: English

DOI: 10.1016/j.mencom.2013.12.007

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