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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 6, Pages 410–411 (Mi mendc2426)

This article is cited in 12 papers

Communications

Polymer-immobilized α,α-bis[bis-3,5-(trifluoromethyl)phenyl]prolinol silyl ether: synthesis and application in the asymmetric α-amination of aldehydes

A. A. Guryev, M. V. Anokhin, A. D. Averin, I. P. Beletskaya

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: α,α-Bis[bis-3,5-(trifluoromethyl)phenyl]prolinol silyl ether anchored onto polystyrene was synthesized and tested in asymmetric α-amination of aldehydes. The catalytic activity and enantioselectivity of the immobilized catalyst persist for 3 cycles.

Language: English

DOI: 10.1016/j.mencom.2015.11.002



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