Communications

IR-spectroscopic manifestation of the diacetyl radical anion produced by irradiation of diacetyl in a dimethyl ether matrix at 7K

E. V. Saenko, D. N. Laikov, V. I. Feldman

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The strongest vibrational feature of a radical anion produced from the diacetyl molecule under radiolysis in a low-temperature dimethyl ether matrix has been characterized for the first time by the analysis of IR- and EPR-spectroscopic data supported by quantum- chemical calculations.

Language: English

DOI: 10.1016/j.mencom.2015.07.011

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