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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 3, Pages 236–238 (Mi mendc2364)

This article is cited in 2 papers

Communications

Interaction of phosphorus trichloride with triethylamine

A. N. Korneva, N. V. Zolotarevaa, V. V. Susheva, A. V. Cherkasova, G. A. Abakumovab

a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b Department of Chemistry, N.I. Lobachevsky Nizhny Novgorod State University, Nizhny Novgorod, Russian Federation

Abstract: Heating of trichlorophosphine with triethylamine in acetonitrile (4h at 80°C) affords 2,2-bis(dichlorophosphino)-N,N-diethylethenamine in 38% yield and oligomeric product containing 60.5% of phosphorus.

Language: English

DOI: 10.1016/j.mencom.2015.05.028



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