This article is cited in 5 papers

Communications

Unexpected formation of (trinitromethyl)pyrazines

I. L. Yudin^a, N. V. Palysaeva^a, B. B. Averkiev^b, A. B. Sheremetev<sup>a

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Treatment of 2-alkoxy-3-methylpyrazines with HNO3 /H2SO4 induces an unusual reaction accompanied by the methyl group nitration with the formation of (trinitromethyl)pyrazines, a structural motif previously unknown in diazine family.

Language: English

DOI: 10.1016/j.mencom.2015.05.011

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